Projects
Area A: SCALMS (Supported Catalytically Active Liquid Metal Solutions)
A01: Characterising the active site in liquid metal catalysts
A01 aims at understanding the catalytic properties of SCALMS and the dynamic behaviour of the active sites at the gas/liquid interface to enable their knowledge-based improvement. We will study model and real-world catalysts in UHV and near-ambient pressure to technical operating conditions. Towards providing a full “depth-resolved” picture, we will employ laboratory- and synchrotron-based X-ray spectroscopic techniques with specific surface or bulk sensitivity. The fundamental studies will reveal details such as the metal distribution in the liquid alloy, its (de-)wetting behaviour on supports, its electronic structure, as well as its behaviour and surface chemistry as a function of temperature and pressure.
Project Leaders
Publications:
A01: Core publications of this project (directly address the working programme of this project)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- Preparation of geometrically highly controlled Ga particle arrays on quasi-planar nanostructured surfaces as a SCALMS model system. A. Hofer, N. Taccardi, M. Moritz, C. Wichmann, S. Hübner, D. Drobek, M. Engelhardt, G. Papastavrou, E. Spiecker, C. Papp, P. Wasserscheid, J. Bachmann, RSC Adv 2023, 13 (6), 4011-4018, https://doi.org/10.1039/D2RA07585G, (Project: A01, A03, A04, A06)
- Temperature-dependent XPS studies on Ga-In alloys through the melting-point. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Surface Science 2022, 717, 122008, http://dx.doi.org/10.1016/j.susc.2021.122008, (Project: A01, A06, M01)
- Surface oxidation-induced restructuring of liquid Pd–Ga SCALMS model catalysts. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Physical Chemistry Chemical Physics 2021, 23 (30), 16324-16333, http://dx.doi.org/10.1039/d1cp02458b, (Project: A01, A06, M01)
A01*: Cooperation publications (publications covering the entire CLINT environment)
A02: Picosecond dynamics of liquid metal catalysts in confinement
The atomic dynamics of metal and alloy droplets of SCALMS systems will be studied in this Project. Using coherent and incoherent quasielastic neutron scattering (QENS), time (pico- to nanoseconds) and length (nanometers) scales relevant for single atom catalysis at the gas/liquid interface will be addressed. The applied methodology allows for decoupling the observation of the atomic dynamics from the slower convection processes and the solid support material hardly contributes to the QENS signal. The QENS data are perfectly suited for validation of atomistic simulations in this CRC. Adapted scattering techniques (XRR, XRD, and (GI)SAXS/SANS) will contribute to structure determination for the whole CRC.
Project Leader
- Prof. Dr. Tobias Unruh (Website: http://www.icsp.nat.fau.de)
Publications:
A02: Core publications of this project (directly address the working programme of this project)
A02*: Cooperation publications (publications covering the entire CLINT environment)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- A New Class of Task-Specific Imidazolium Salts and Ionic Liquids and Their Corresponding Transition-Metal Complexes for Immobilization on Electrochemically Active Surfaces. V. Seidl, A. H. Romero, F. W. Heinemann, A. Scheurer, C. S. Vogel, T. Unruh, P. Wasserscheid, K. Meyer, Chemistry – A European Journal 2022, 28 (20), e202200100, https://doi.org/10.1002/chem.202200100, (Project: A02*, B01, C01)
- Thermochemical and Structural Studies of New Chiral and Achiral Long Alkyl Chain Functionalized Imidazolinium Ionic Liquids. V. Seidl, M. Sternberg, F. W. Heinemann, M. Schmiele, T. Unruh, P. Wasserscheid, K. Meyer, Crystal Growth & Design 2021, 21 (11), 6276-6288, http://dx.doi.org/10.1021/acs.cgd.1c00734, (Project: A02*, B01)
- A Self‐Ordered Nanostructured Transparent Electrode of High Structural Quality and Corresponding Functional Performance. D. Döhler, A. Triana, P. Büttner, F. Scheler, E. S. A. Goerlitzer, J. Harrer, A. Vasileva, E. Metwalli, W. Gruber, T. Unruh, A. Manshina, N. Vogel, J. Bachmann, I. Mínguez‐Bacho, Small 2021, 17 (20), 2100487, http://dx.doi.org/10.1002/smll.202100487, (Project: A02*, A04, B03)
A03: Scale-bridging tomography and in situ microscopy of SCALMS
Project A03 addresses the temperature-dependent phase stability of SCALMS, the liquid alloy distribution, the surface composition, and the wetting behaviour in porous support materials. For this purpose, we will use analytical and in situ transmission electron microscopy (TEM) as well as scale-bridging tomography techniques, ranging from atom probe tomography (APT) and electron tomography (ET) to X-ray nanotomography (NanoCT). The project includes in situ studies with high spatial resolution of model nanoalloys at near operation conditions, three-dimensional chemical and structural analysis of SCALMS with high-resolution through correlative TEM/APT, and scale-bridging correlative 3D analysis of SCALMS after catalytic operation.
Project Leaders
Publications:
A03: Core publications of this project (directly address the working programme of this project)
- Expanding accessible 3D sample size in lab-based X-ray nanotomography without compromising resolution. S. Englisch, J. Wirth, D. Drobek, B. Apeleo Zubiri, E. Spiecker, Precision Engineering 2023, 82, 169-183, https://doi.org/10.1016/j.precisioneng.2023.02.011, (Project: A03)
- From Meso to Macro: Controlling Hierarchical Porosity in Supraparticle Powders. U. Sultan, A. Götz, C. Schlumberger, D. Drobek, G. Bleyer, T. Walter, E. Löwer, U. A. Peuker, M. Thommes, E. Spiecker, B. Apeleo Zubiri, A. Inayat, N. Vogel, Small 2023, 2300241, http://dx.doi.org/10.1002/smll.202300241, (Project: A03, B03)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- Preparation of geometrically highly controlled Ga particle arrays on quasi-planar nanostructured surfaces as a SCALMS model system. A. Hofer, N. Taccardi, M. Moritz, C. Wichmann, S. Hübner, D. Drobek, M. Engelhardt, G. Papastavrou, E. Spiecker, C. Papp, P. Wasserscheid, J. Bachmann, RSC Adv 2023, 13 (6), 4011-4018, https://doi.org/10.1039/D2RA07585G, (Project: A01, A03, A04, A06)
- Sub-Kelvin thermometry for evaluating the local temperature stability within in situ TEM gas cells. B. Fritsch, M. Wu, A. Hutzler, D. Zhou, R. Spruit, L. Vogl, J. Will, H. Hugo Pérez Garza, M. März, M. P. M. Jank, E. Spiecker, Ultramicroscopy 2022, 235, 113494, https://doi.org/10.1016/j.ultramic.2022.113494, (Project: A03)
- GaPt Supported Catalytically Active Liquid Metal Solution Catalysis for Propane Dehydrogenation-Support Influence and Coking Studies. N. Raman, M. Wolf, M. Heller, N. Heene-Würl, N. Taccardi, M. Haumann, P. Felfer, P. Wasserscheid, ACS Catal 2021, 11 (21), 13423-13433, https://doi.org/10.1021/acscatal.1c01924, (Project: A03, A06, B06*)
- Unraveling Structural Details in Ga-Pd SCALMS Systems Using Correlative Nano-CT, 360° Electron Tomography and Analytical TEM. J. Wirth, S. Englisch, D. Drobek, B. Apeleo Zubiri, M. Wu, N. Taccardi, N. Raman, P. Wasserscheid, E. Spiecker, Catalysts 2021, 11 (7), 810, http://dx.doi.org/10.3390/catal11070810, (Project: A03, A06)
A03*: Cooperation publications (publications covering the entire CLINT environment)
- 3D analysis of equally X-ray attenuating mineralogical phases utilizing a correlative tomographic workflow across multiple length scales. S. Englisch, R. Ditscherlein, T. Kirstein, L. Hansen, O. Furat, D. Drobek, T. Leißner, B. Apeleo Zubiri, A. P. Weber, V. Schmidt, U. A. Peuker, E. Spiecker, Powder Technology 2023, 419, 118343, https://doi.org/10.1016/j.powtec.2023.118343, (Project: A03*)
- Single Atoms in Photocatalysis: Low Loading Is Good Enough! S. Qin, J. Will, H. Kim, N. Denisov, S. Carl, E. Spiecker, P. Schmuki, ACS Energy Letters 2023, 8 (2), 1209-1214, http://dx.doi.org/10.1021/acsenergylett.2c02801, (Project: A03*)
A04: Tuneable supports and geometry effects in SCALMS catalysis
Catalysis in SCALMS takes place at the gas/liquid interface. However, standard preparation methods for SCALMS do not control the liquid interface area and, thus, this parameter is mostly unknown, at least under reaction conditions. Project A04 targets the preparation and catalytic application of SCALMS materials with ordered, regularly spaced liquid metal droplets of uniform size. For this purpose, dimples (radius of curvature between 10 and 200 nm depending on preparation) will be prepared on planar Al or Ti substrates by anodisation and filled with alloy droplets. Their size will be varied to generate model systems applicable to theoretical description and SCALMS microreactors with optimised specific surface areas.
Project Leader
Publications:
A04: Core publications of this project (directly address the working programme of this project)
- Nature-inspired functional porous materials for low-concentration biomarker detection. I. Papiano, S. De Zio, A. Hofer, M. Malferrari, I. Mínguez Bacho, J. Bachmann, S. Rapino, N. Vogel, G. Magnabosco, Materials Horizons 2023, http://dx.doi.org/10.1039/D3MH00553D, (Project: A04, B03).
- Preparation of geometrically highly controlled Ga particle arrays on quasi-planar nanostructured surfaces as a SCALMS model system. A. Hofer, N. Taccardi, M. Moritz, C. Wichmann, S. Hübner, D. Drobek, M. Engelhardt, G. Papastavrou, E. Spiecker, C. Papp, P. Wasserscheid, J. Bachmann, RSC Adv 2023, 13 (6), 4011-4018, https://doi.org/10.1039/D2RA07585G, (Project: A01, A03, A04, A06)
- A Self‐Ordered Nanostructured Transparent Electrode of High Structural Quality and Corresponding Functional Performance. D. Döhler, A. Triana, P. Büttner, F. Scheler, E. S. A. Goerlitzer, J. Harrer, A. Vasileva, E. Metwalli, W. Gruber, T. Unruh, A. Manshina, N. Vogel, J. Bachmann, I. Mínguez‐Bacho, Small 2021, 17 (20), 2100487, http://dx.doi.org/10.1002/smll.202100487, (Project: A02*, A04, B03)
A04*: Cooperation publications (publications covering the entire CLINT environment)
- Bis-polyethylene glycol-functionalized imidazolium ionic liquids: A multi-method approach towards bulk and surface properties. V. Seidl, M. Bosch, U. Paap, M. Livraghi, Z. Zhai, C. R. Wick, T.-M. Koller, P. Wasserscheid, F. Maier, A.-S. Smith, J. Bachmann, H.-P. Steinrück, K. Meyer, Journal of Ionic Liquids 2022, 2 (2), 100041, http://dx.doi.org/10.1016/j.jil.2022.100041, (Project: A04*, B01, B04, M02)
- From Sticky to Slippery: Self-Functionalizing Lubricants for In Situ Fabrication of Liquid-Infused Surfaces. S. Chiera, V. M. Koch, G. Bleyer, T. Walter, C. Bittner, J. Bachmann, N. Vogel, ACS Applied Materials & Interfaces 2022, 14 (14), 16735-16745, http://dx.doi.org/10.1021/acsami.2c02390, (Project: A04*, B03)
A05: Textural properties and wetting behaviour of new SCALMS
Project A05 deals with experimental studies to understand and optimise the wetting of liquid alloys on porous support materials. We explore how structure and catalytic performance of SCALMS are affected by the interplay between preparation, surface chemical properties and support texture. For this, we will develop targeted, adsorption-based methodologies and novel liquid intrusion techniques for (i) a reliable textural characterisation of SCALMS and meso-macroporous supports and (ii) for assessing the wetting behaviour of liquid metal solutions in the supports. This information will enable a knowledge-based selection of support materials and pore structures for maximising the gas/alloy interface of SCALMS and, thereby, the volumetric productivity.
Project Leader
Publications:
A05: Core publications of this project (directly address the working programme of this project)
- Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems. T. Solymosi, M. Geißelbrecht, S. Mayer, M. Auer, P. Leicht, M. Terlinden, P. Malgaretti, A. Bösmann, P. Preuster, J. Harting, M. Thommes, N. Vogel, P. Wasserscheid, Sci Adv 2022, 8 (46), eade3262, https://doi.org/10.1126/sciadv.ade3262, (Project: A05, A06*, B03, M04)
- Influence of Support Texture and Reaction Conditions on the Accumulation and Activity in the Gas-Phase Aldol Condensation of n-Pentanal on Porous Silica. M. Schörner, S. Kämmerle, D. Wisser, B. Baier, M. Hartmann, M. Thommes, R. Franke, M. Haumann, Reaction Chemistry & Engineering 2022, 7 (11), 2445-2459, http://dx.doi.org/10.1039/d2re00143h, (Project: A05, B05, B06)
- Supraparticles for Bare‐Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. J. Reichstein, S. Schötz, M. Macht, S. Maisel, N. Stockinger, C. C. Collados, K. Schubert, D. Blaumeiser, S. Wintzheimer, A. Görling, M. Thommes, D. Zahn, J. Libuda, T. Bauer, K. Mandel, Advanced Functional Materials 2022, 32 (22), 2112379, http://dx.doi.org/10.1002/adfm.202112379, (Project: A05, C03*, C05*, M01*, M03*)
- Gas‐Phase Hydroformylation Using Supported Ionic Liquid Phase (SILP) Catalysts – Influence of Support Texture on Effective Kinetics. M. Schörner, P. Rothgängel, K. Mitländer, D. Wisser, M. Thommes, M. Haumann, ChemCatChem 2021, 13 (19), 4192-4200, http://dx.doi.org/10.1002/cctc.202100743, (Project: A05, B05, B06)
A05*: Cooperation publications (publications covering the entire CLINT environment)
A06: Enhancing poisoning resistance and catalyst stability in dehydrogenation reactions through SCALMS
A06 focuses on the technical dimension of SCALMS by exploring quantitatively the expected enhanced poisoning resistance and stability in dehydrogenation catalysis. For the specific case of isobutane dehydrogenation, we will perform systematic poisoning experiments under surface science and technical conditions. The data will be compared to traditional catalysts. Spectroscopic and reaction engineering studies will be applied to determine the concentration, reactivity, and regenerability of active sites of the SCALMS systems after contact with defined amounts of traditional poisons or after exposure to conditions favouring coke formation. We will also investigate ternary SCALMS to elucidate the effect of further alloying and dissolution on the adsorption strengths, reactivity, and stability.
Project Leaders
Publications:
A06: Core publications of this project (directly address the working programme of this project)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- Preparation of geometrically highly controlled Ga particle arrays on quasi-planar nanostructured surfaces as a SCALMS model system. A. Hofer, N. Taccardi, M. Moritz, C. Wichmann, S. Hübner, D. Drobek, M. Engelhardt, G. Papastavrou, E. Spiecker, C. Papp, P. Wasserscheid, J. Bachmann, RSC Adv 2023, 13 (6), 4011-4018, https://doi.org/10.1039/D2RA07585G, (Project: A01, A03, A04, A06)
- Temperature-dependent XPS studies on Ga-In alloys through the melting-point. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Surface Science 2022, 717, 122008, http://dx.doi.org/10.1016/j.susc.2021.122008, (Project: A01, A06, M01)
- GaPt Supported Catalytically Active Liquid Metal Solution Catalysis for Propane Dehydrogenation-Support Influence and Coking Studies. N. Raman, M. Wolf, M. Heller, N. Heene-Würl, N. Taccardi, M. Haumann, P. Felfer, P. Wasserscheid, ACS Catal 2021, 11 (21), 13423-13433, https://doi.org/10.1021/acscatal.1c01924, (Project: A03, A06, B06*)
- Surface oxidation-induced restructuring of liquid Pd–Ga SCALMS model catalysts. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Physical Chemistry Chemical Physics 2021, 23 (30), 16324-16333, http://dx.doi.org/10.1039/d1cp02458b, (Project: A01, A06, M01)
- Unraveling Structural Details in Ga-Pd SCALMS Systems Using Correlative Nano-CT, 360° Electron Tomography and Analytical TEM. J. Wirth, S. Englisch, D. Drobek, B. Apeleo Zubiri, M. Wu, N. Taccardi, N. Raman, P. Wasserscheid, E. Spiecker, Catalysts 2021, 11 (7), 810, http://dx.doi.org/10.3390/catal11070810, (Project: A03, A06)
A06*: Cooperation publications (publications covering the entire CLINT environment)
- Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems. T. Solymosi, M. Geißelbrecht, S. Mayer, M. Auer, P. Leicht, M. Terlinden, P. Malgaretti, A. Bösmann, P. Preuster, J. Harting, M. Thommes, N. Vogel, P. Wasserscheid, Sci Adv 2022, 8 (46), eade3262, https://doi.org/10.1126/sciadv.ade3262, (Project: A05, A06*, B03, M04)
Area B: Interface-enhanced SILP (Supported Ionic Liquid Phase)
B01: Task-specific ionic liquids and their Group 10 metal coordination complexes for Interface-enhanced catalysis
Project B01 focuses on the design and synthesis of functionalised and task-specific ILs, with the aim (i) to tailor support/IL interfaces and (ii) to develop electrocatalytically active interface-enhanced SILPs. The latter concept will combine catalytic functionalities operating at both the gas/IL and the IL/solid interfaces for the electrochemical production of hydrogen from water (or protons) and the hydrogenation of divers C=C and C=O moieties in selected substrates. These two processes shall be controlled by the incorporation of identical task-specific structural motifs in the IL and in the active transition metal catalyst. The long-term objective will be the direct electrocatalytic hydrogenation of substrates in a ‘tandem-like’ system.
Project Leaders
Publlications:
B01: Core publications of this project (directly address the working programme of this project)
- Direct Correlation of Surface Tension and Surface Composition of Ionic Liquid Mixtures-A Combined Vacuum Pendant Drop and Angle-Resolved X-ray Photoelectron Spectroscopy Study. U. Paap, V. Seidl, K. Meyer, F. Maier, H.-P. Steinrück, Molecules 2022, 27 (23), 8561, https://doi.org/10.3390/molecules27238561, (Project: B01, B04)
- Bis-polyethylene glycol-functionalized imidazolium ionic liquids: A multi-method approach towards bulk and surface properties. V. Seidl, M. Bosch, U. Paap, M. Livraghi, Z. Zhai, C. R. Wick, T.-M. Koller, P. Wasserscheid, F. Maier, A.-S. Smith, J. Bachmann, H.-P. Steinrück, K. Meyer, Journal of Ionic Liquids 2022, 2 (2), 100041, http://dx.doi.org/10.1016/j.jil.2022.100041, (Project: A04*, B01, B04, M02)
- Combined Surface Light Scattering and Pendant-Drop Experiments for the Determination of Viscosity and Surface Tension of High-Viscosity Fluids Demonstrated for Ionic Liquids. Z. Zhai, J. H. Jander, A. Bergen, J. Cui, K. Meyer, T.-M. Koller, International Journal of Thermophysics 2022, 43 (12), 178, http://dx.doi.org/10.1007/s10765-022-03103-z, (Project: B01, B04)
- A New Class of Task-Specific Imidazolium Salts and Ionic Liquids and Their Corresponding Transition-Metal Complexes for Immobilization on Electrochemically Active Surfaces. V. Seidl, A. H. Romero, F. W. Heinemann, A. Scheurer, C. S. Vogel, T. Unruh, P. Wasserscheid, K. Meyer, Chemistry – A European Journal 2022, 28 (20), e202200100, https://doi.org/10.1002/chem.202200100, (Project: A02*, B01, C01)
- Thermochemical and Structural Studies of New Chiral and Achiral Long Alkyl Chain Functionalized Imidazolinium Ionic Liquids. V. Seidl, M. Sternberg, F. W. Heinemann, M. Schmiele, T. Unruh, P. Wasserscheid, K. Meyer, Crystal Growth & Design 2021, 21 (11), 6276-6288, http://dx.doi.org/10.1021/acs.cgd.1c00734, (Project: A02*, B01)
B01*: Cooperation publications (publications covering the entire CLINT environment)
B02: Functionalised metal complexes for tuning their surface enrichment and reactivity at ionic liquid interfaces
We aim to design functionalised redox active metal complexes to control their enrichment and orientation at ILs interfaces, i.e. the exposure of active sites to the reactants and thus, control their reactivity. Targeted will be binding and hydrogenation/reduction of CO2 or other C=O functionalities by Pt, Pd, Ru and Ni complexes of bi-, tri- and tetradentate pincer-like or macrocyclic ligands. Systematic variation of substituents will tune charge, polarity, coordination equilibria and redox properties of complexes, affecting interactions with ILs and reactants, leading to catalytic activity. We will also study kinetics and thermodynamics of processes in ILs and, for comparison, conventional solvents by variety of techniques, including high-pressure and cryo-methodology.
Project Leaders
Publications:
B02: Core publications of this project (directly address the working programme of this project)
B02*: Cooperation publications (publications covering the entire CLINT environment)
B03: Support design for enhanced catalytic activity of SILP systems
Project B03 will develop silica-based support materials with tailored porosity and surface properties to explore the catalytic potential of interface-enhanced SILPs. We will control the wettability and film formation of the ILs on the solid support via surface functionalisation and the introduction of hierarchical porosity. These tailored supports will maximise the IL wettability and film stability while ensuring efficient mass transport by preventing pore flooding, also under reaction conditions. We will take advantage of the homogeneous IL films with controlled thickness and tailored surface functionality to control the catalyst position relative to the gas/liquid and liquid/solid interface to elucidate differences in activity and fundamentally understand SILP performance.
Project Leaders
Publications:
B03: Core publications of this project (directly address the working programme of this project)
- Nature-inspired functional porous materials for low-concentration biomarker detection. I. Papiano, S. De Zio, A. Hofer, M. Malferrari, I. Mínguez Bacho, J. Bachmann, S. Rapino, N. Vogel, G. Magnabosco, Materials Horizons 2023, http://dx.doi.org/10.1039/D3MH00553D, (Project: A04, B03).
- From Meso to Macro: Controlling Hierarchical Porosity in Supraparticle Powders. U. Sultan, A. Götz, C. Schlumberger, D. Drobek, G. Bleyer, T. Walter, E. Löwer, U. A. Peuker, M. Thommes, E. Spiecker, B. Apeleo Zubiri, A. Inayat, N. Vogel, Small 2023, 2300241, http://dx.doi.org/10.1002/smll.202300241, (Project: A03, B03)
- Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems. T. Solymosi, M. Geißelbrecht, S. Mayer, M. Auer, P. Leicht, M. Terlinden, P. Malgaretti, A. Bösmann, P. Preuster, J. Harting, M. Thommes, N. Vogel, P. Wasserscheid, Sci Adv 2022, 8 (46), eade3262, https://doi.org/10.1126/sciadv.ade3262, (Project: A05, A06*, B03, M04)
- From Sticky to Slippery: Self-Functionalizing Lubricants for In Situ Fabrication of Liquid-Infused Surfaces. S. Chiera, V. M. Koch, G. Bleyer, T. Walter, C. Bittner, J. Bachmann, N. Vogel, ACS Applied Materials & Interfaces 2022, 14 (14), 16735-16745, http://dx.doi.org/10.1021/acsami.2c02390, (Project: A04*, B03)
- Materials with Hierarchical Porosity Enhance the Stability of Infused Ionic Liquid Films. Y. Galvan, J. Bauernfeind, P. Wolf, R. Zarraga, M. Haumann, N. Vogel, ACS Omega 2021, 6 (32), 20956-20965, https://doi.org/10.1021/acsomega.1c02405, (Project: B03, B06*)
B03*: Cooperation publications (publications covering the entire CLINT environment)
- A Self‐Ordered Nanostructured Transparent Electrode of High Structural Quality and Corresponding Functional Performance. D. Döhler, A. Triana, P. Büttner, F. Scheler, E. S. A. Goerlitzer, J. Harrer, A. Vasileva, E. Metwalli, W. Gruber, T. Unruh, A. Manshina, N. Vogel, J. Bachmann, I. Mínguez‐Bacho, Small 2021, 17 (20), 2100487, http://dx.doi.org/10.1002/smll.202100487, (Project: A02*, A04, B03)
B04: Properties of the gas/liquid interface of Interface-enhanced SILP systems
We aim at understanding the fundamental processes that determine the properties of the gas/liquid interface of Interface-enhanced SILPs. Towards this aim, the Steinrück and Koller groups will apply X-ray photoelectron spectroscopy under ultraclean conditions and the pendant drop method as well as surface light scattering under reaction conditions. This enables to develop relationships between the surface properties on the nanometre scale and the macroscopic properties surface tension, viscosity and dynamics of surface fluctuations. Based on this concerted characterisation, we envisage to identify those factors which are responsible for the enrichment of catalytic metal complexes at IL interfaces.
Project Leaders
Publications:
B04: Core publications of this project (directly address the working programme of this project)
- Surface tension and viscosity of binary ionic liquid mixtures from high vacuum up to pressures of 10 MPa. Z. Zhai, U. Paap, A. Gezmis, F. Maier, H.-P. Steinrück, T. M. Koller, Journal of Molecular Liquids 2023, 386, 122388, https://doi.org/10.1016/j.molliq.2023.122388, (Project: B04).
- High-Temperature Measurements on Viscosity and Surface Tension of the Ionic Liquid 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]) up to 473 K. Z. Zhai, T. M. Koller, International Journal of Thermophysics 2023, 44 (8), 118, https://doi.org/10.1007/s10765-023-03226-x, (Project: B04).
- Structure and Surface Behavior of Rh Complexes in Ionic Liquids Studied Using Angle-Resolved X-ray Photoelectron Spectroscopy. D. Hemmeter, U. Paap, F. Maier, H.-P. Steinrück, Catalysts 2023, 13 (5), 871, http://dx.doi.org/10.3390/catal13050871, (Project: B04)
- Influence of dissolved argon or carbon dioxide on the viscosity and surface tension of the imidazolium-based ionic liquids [OMIM][PF6] or [m(PEG2)2IM]I. Z. Zhai, T.-M. Koller, Journal of Molecular Liquids 2023, 377, 121491, https://doi.org/10.1016/j.molliq.2023.121491, (Project: B04)
- The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design. D. Hemmeter, D. Kremitzl, P. S. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, Chemistry – A European Journal 2023, 29 (3), http://dx.doi.org/10.1002/chem.202204023, (Project: B04, C01)
- Direct Correlation of Surface Tension and Surface Composition of Ionic Liquid Mixtures-A Combined Vacuum Pendant Drop and Angle-Resolved X-ray Photoelectron Spectroscopy Study. U. Paap, V. Seidl, K. Meyer, F. Maier, H.-P. Steinrück, Molecules 2022, 27 (23), 8561, https://doi.org/10.3390/molecules27238561, (Project: B01, B04)
- Bis-polyethylene glycol-functionalized imidazolium ionic liquids: A multi-method approach towards bulk and surface properties. V. Seidl, M. Bosch, U. Paap, M. Livraghi, Z. Zhai, C. R. Wick, T.-M. Koller, P. Wasserscheid, F. Maier, A.-S. Smith, J. Bachmann, H.-P. Steinrück, K. Meyer, Journal of Ionic Liquids 2022, 2 (2), 100041, http://dx.doi.org/10.1016/j.jil.2022.100041, (Project: A04*, B01, B04, M02)
- Probing Surface and Interfacial Tension of Ionic Liquids in Vacuum with the Pendant Drop and Sessile Drop Method. U. Paap, B. Kreß, H.-P. Steinrück, F. Maier, Int J Mol Sci 2022, 23 (21), 13158, https://doi.org/10.3390/ijms232113158, (Project: B04)
- Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS. D. Hemmeter, U. Paap, N. Taccardi, J. Mehler, P. S. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, ChemPhysChem 2022, 24 (2), http://dx.doi.org/10.1002/cphc.202200391, (Project: B04, C01)
- Combined Surface Light Scattering and Pendant-Drop Experiments for the Determination of Viscosity and Surface Tension of High-Viscosity Fluids Demonstrated for Ionic Liquids. Z. Zhai, J. H. Jander, A. Bergen, J. Cui, K. Meyer, T.-M. Koller, International Journal of Thermophysics 2022, 43 (12), 178, http://dx.doi.org/10.1007/s10765-022-03103-z, (Project: B01, B04)
B04*: Cooperation publications (publications covering the entire CLINT environment)
B05: Solid-state NMR investigations of SILP-based catalysts
Project B05 aims at understanding the properties of the liquid/solid interface of Interface-enhanced SILPs using solid-state NMR spectroscopy. We will determine the dynamics of the IL and its interactions with the support, as well as the distance between the catalyst and the support by implementing advanced solid-state NMR methods, including 2D heteronuclear correlation and REDOR techniques. Ultimately, Parahydrogen Induced Polarisation (PHIP) in a Magic Angle Spinning probe will be developed as a novel tool to probe with enhanced sensitivity hydrogenation reactions in SILP catalysts in situ and operando. Active catalyst components, reaction intermediates and side products can thus be identified.
Project Leaders
Publications:
B05: Core publications of this project (directly address the working programme of this project)
- Wetting Behavior and Support Interactions in Imidazolium-Based Supported Ionic Liquid Phase Materials─A Systematic Study by Solid-State Nuclear Magnetic Resonance Spectroscopy. M. Frosch, C. L. Tavera Mendez, A. B. Koch, M. Schörner, M. Haumann, M. Hartmann, D. Wisser, The Journal of Physical Chemistry C 2023, 127 (19), 9196-9204, https://doi.org/10.1021/acs.jpcc.2c07795, (Project: B05, B06)
- Influence of Support Texture and Reaction Conditions on the Accumulation and Activity in the Gas-Phase Aldol Condensation of n-Pentanal on Porous Silica. M. Schörner, S. Kämmerle, D. Wisser, B. Baier, M. Hartmann, M. Thommes, R. Franke, M. Haumann, Reaction Chemistry & Engineering 2022, 7 (11), 2445-2459, http://dx.doi.org/10.1039/d2re00143h, (Project: A05, B05, B06)
- Continuous Gas-Phase Synthesis of Oxymethylene Dimethyl Ethers Using Supported Ionic Liquid Phase Catalysts. M. Aubermann, M. Haumann, D. Wisser, P. Wasserscheid, ACS Sustainable Chemistry & Engineering 2022, 10 (21), 6973-6980, http://dx.doi.org/10.1021/acssuschemeng.2c00004, (Project: B05, B06*, C01*)
- Gas‐Phase Hydroformylation Using Supported Ionic Liquid Phase (SILP) Catalysts – Influence of Support Texture on Effective Kinetics. M. Schörner, P. Rothgängel, K. Mitländer, D. Wisser, M. Thommes, M. Haumann, ChemCatChem 2021, 13 (19), 4192-4200, http://dx.doi.org/10.1002/cctc.202100743, (Project: A05, B05, B06)
B05*: Cooperation publications (publications covering the entire CLINT environment)
B06: Influencing SILP catalyst performance by the location of reaction
In Project B06, we will elucidate the relation between the position of the active molecular complex in the SILP material and the resulting activity, selectivity, and stability of the catalyst. We envisage that for e.g poorly soluble substrates the reaction is still fast if the active species is located at the gas/IL interface and slow if the active species is located in the IL bulk or at the IL/support interface. We will determine solubility of different substrates in ILs and test competitive conversion of mixed feeds containing substrates with strongly differing solubility. Systematic kinetic tests will be performed varying the IL (chain length and functionalisation), the catalyst (ligand variation) and the operation conditions.
Project Leaders
Publications:
B06: Core publications of this project (directly address the working programme of this project)
- Wetting Behavior and Support Interactions in Imidazolium-Based Supported Ionic Liquid Phase Materials─A Systematic Study by Solid-State Nuclear Magnetic Resonance Spectroscopy. M. Frosch, C. L. Tavera Mendez, A. B. Koch, M. Schörner, M. Haumann, M. Hartmann, D. Wisser, The Journal of Physical Chemistry C 2023, 127 (19), 9196-9204, https://doi.org/10.1021/acs.jpcc.2c07795, (Project: B05, B06)
- Wilkinson-type catalysts in ionic liquids for hydrogenation of small alkenes: understanding and improving catalyst stability. E. Kratzer, S. Schoetz, S. Maisel, D. Blaumeiser, S. Khan Antara, L. Ewald, D. Dotzel, M. Haumann, A. Görling, W. Korth, A. Jess, T. Retzer, Catal Sci Technol 2023, 13 (7), 2053-2069, http://dx.doi.org/10.1039/d2cy02058k, (Project: B06, M01)
- Influence of Support Texture and Reaction Conditions on the Accumulation and Activity in the Gas-Phase Aldol Condensation of n-Pentanal on Porous Silica. M. Schörner, S. Kämmerle, D. Wisser, B. Baier, M. Hartmann, M. Thommes, R. Franke, M. Haumann, Reaction Chemistry & Engineering 2022, 7 (11), 2445-2459, http://dx.doi.org/10.1039/d2re00143h, (Project: A05, B05, B06)
- Gas‐Phase Hydroformylation Using Supported Ionic Liquid Phase (SILP) Catalysts – Influence of Support Texture on Effective Kinetics. M. Schörner, P. Rothgängel, K. Mitländer, D. Wisser, M. Thommes, M. Haumann, ChemCatChem 2021, 13 (19), 4192-4200, http://dx.doi.org/10.1002/cctc.202100743, (Project: A05, B05, B06)
B06*: Cooperation publications (publications covering the entire CLINT environment)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- Measurement of Minute Liquid Volumes of Chiral Molecules Using In-Fiber Polarimetry. F. Schorn, A. Essert, Y. Zhong, S. Abdullayev, K. Castiglione, M. Haumann, N. Y. Joly, Analytical Chemistry 2023, 95 (6), 3204-3209, https://doi.org/10.1021/acs.analchem.2c03347, (Project: B06*)
- Influencing the Product Distribution in Citral Hydrogenation Using Ionic Liquid Modified Cu Catalysts. L. Naicker, M. Schörner, D. Kremitzl, H. B. Friedrich, M. Haumann, P. Wasserscheid, ChemCatChem 2022, 14 (19), e202200388, http://dx.doi.org/10.1002/cctc.202200388, (Project: B06*, C01*)
- Continuous Gas-Phase Synthesis of Oxymethylene Dimethyl Ethers Using Supported Ionic Liquid Phase Catalysts. M. Aubermann, M. Haumann, D. Wisser, P. Wasserscheid, ACS Sustainable Chemistry & Engineering 2022, 10 (21), 6973-6980, http://dx.doi.org/10.1021/acssuschemeng.2c00004, (Project: B05, B06*, C01*)
- Improving the Performance of Supported Ionic Liquid Phase Catalysts for the Ultra-Low-Temperature Water Gas Shift Reaction Using Organic Salt Additives. P. Wolf, C. R. Wick, J. Mehler, D. Blaumeiser, S. Schötz, T. Bauer, J. Libuda, D. Smith, A.-S. Smith, M. Haumann, ACS Catal 2022, 12 (9), 5661-5672, https://doi.org/10.1021/acscatal.1c05979, (Project: B06*, C03*, C05*, M02)
- GaPt Supported Catalytically Active Liquid Metal Solution Catalysis for Propane Dehydrogenation-Support Influence and Coking Studies. N. Raman, M. Wolf, M. Heller, N. Heene-Würl, N. Taccardi, M. Haumann, P. Felfer, P. Wasserscheid, ACS Catal 2021, 11 (21), 13423-13433, https://doi.org/10.1021/acscatal.1c01924, (Project: A03, A06, B06*)
- Materials with Hierarchical Porosity Enhance the Stability of Infused Ionic Liquid Films. Y. Galvan, J. Bauernfeind, P. Wolf, R. Zarraga, M. Haumann, N. Vogel, ACS Omega 2021, 6 (32), 20956-20965, https://doi.org/10.1021/acsomega.1c02405, (Project: B03, B06*)
Area C: Advanced SCILL (Solid Catalysts with Ionic Liquid Layer)
C01: SCILL with mono- and bifunctional ionic liquids for selective hydrogenation reactions
Project C01 deals with the modification of alumina-supported Pt and Pd catalysts with ILs that carry one or several functionalities. By specific interaction of the IL and its functionalities with the solid catalyst, a ligand-like IL effect is expected which strongly alters activity and selectivity of the active sites of the supported nanoparticles. The ILs will be prepared in highest purity and are also provided to the partner projects C02–C05. The prepared catalysts will be tested in competitive gas phase hydrogenation reactions comparing SCILL systems with non-functionalised ILs, functionalised ILs and IL mixtures. This project will provide de-tailed kinetic data (activity, selectivity, chemoselectivity) of Advanced SCILL catalysts and will explore the stability of IL functionalities under reaction conditions.
Project Leaders
Publications:
C01: Core publications of this project (directly address the working programme of this project)
- The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design. D. Hemmeter, D. Kremitzl, P. S. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, Chemistry – A European Journal 2023, 29 (3), http://dx.doi.org/10.1002/chem.202204023, (Project: B04, C01)
- Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS. D. Hemmeter, U. Paap, N. Taccardi, J. Mehler, P. S. Schulz, P. Wasserscheid, F. Maier, H.-P. Steinrück, ChemPhysChem 2022, 24 (2), http://dx.doi.org/10.1002/cphc.202200391, (Project: B04, C01)
- Modifying the Electrocatalytic Selectivity of Oxidation Reactions with Ionic Liquids. T. Yang, J. Yang, X. Deng, E. Franz, L. Fromm, N. Taccardi, Z. Liu, A. Görling, P. Wasserscheid, O. Brummel, J. Libuda, Angew Chem Int Ed Engl 2022, 61 (29), e202202957, https://doi.org/10.1002/anie.202202957, (Project: C01, C05, M01)
- A New Class of Task-Specific Imidazolium Salts and Ionic Liquids and Their Corresponding Transition-Metal Complexes for Immobilization on Electrochemically Active Surfaces. V. Seidl, A. H. Romero, F. W. Heinemann, A. Scheurer, C. S. Vogel, T. Unruh, P. Wasserscheid, K. Meyer, Chemistry – A European Journal 2022, 28 (20), e202200100, https://doi.org/10.1002/chem.202200100, (Project: A02*, B01, C01)
C01*: Cooperation publications (publications covering the entire CLINT environment)
- Influencing the Product Distribution in Citral Hydrogenation Using Ionic Liquid Modified Cu Catalysts. L. Naicker, M. Schörner, D. Kremitzl, H. B. Friedrich, M. Haumann, P. Wasserscheid, ChemCatChem 2022, 14 (19), e202200388, http://dx.doi.org/10.1002/cctc.202200388, (Project: B06*, C01*)
- Continuous Gas-Phase Synthesis of Oxymethylene Dimethyl Ethers Using Supported Ionic Liquid Phase Catalysts. M. Aubermann, M. Haumann, D. Wisser, P. Wasserscheid, ACS Sustainable Chemistry & Engineering 2022, 10 (21), 6973-6980, http://dx.doi.org/10.1021/acssuschemeng.2c00004, (Project: B05, B06*, C01*)
- B/N-doped carbon sheets from a new ionic liquid with excellent sorption properties for methylene blue. J. Mehler, M. Ermer, U. Paap, B. S. J. Heller, F. Maier, H.-P. Steinrück, M. Hartmann, C. Korte, P. S. Schulz, P. Wasserscheid, Journal of Ionic Liquids 2021, 1 (1), 1-9, http://dx.doi.org/10.1016/j.jil.2021.100004, (Project: C01*)
C02: Surface and interface science studies of Advanced SCILL systems
We aim at understanding the fundamental processes and the chemical/morphological stability of IL/solid interfaces in Advanced SCILLs. We will proceed in three steps: for non-functionalised and functionalised ILs, we will investigate (a) the chemical interaction and the wetting behaviour of (ultra)thin IL films on the supporting solid on a wide range of well-defined substrates, (b)the stability of Advanced SCILL systems from the point of view of interface chemistry and morphology, and finally, (c) strategies to control and to switch the adsorption and wetting behaviour. Using ARXPS, STM, and AFM, we will extract interface compositions, depth profiles, chemical states, adsorption geometries and growth behaviour.
Project Leaders
Publications:
C02: Core publications of this project (directly address the working programme of this project)
- Structure and Reactivity of the Ionic Liquid [C1C1Im][Tf2N] on Cu(111). R. Adhikari, S. Massicot, L. Fromm, T. Talwar, A. Gezmis, M. Meusel, A. Bayer, S. Jaekel, F. Maier, A. Görling, H.-P. Steinrück, Topics in Catalysis 2023, 1-18, https://doi.org/10.1007/s11244-023-01801-y, (Project: C02, M01)
- On-Surface Metathesis of an Ionic Liquid on Ag(111). S. Massicot, T. Sasaki, M. Lexow, F. Maier, S. Kuwabata, H.-P. Steinrück, Chemistry – A European Journal 2022, 28 (28), e202200167, https://doi.org/10.1002/chem.202200167, (Project: C02)
- The Effect of Ambient Conditions on the Potential Screening at Ionic Liquid – Electrode Interfaces. F. Greco, D. Hemmeter, S. Shin, H.-P. Steinrück, F. Maier, Journal of Ionic Liquids 2022, 2 (1), 100019, http://dx.doi.org/10.1016/j.jil.2022.100019, (Project: C02)
- Adsorption, Wetting, Growth, and Thermal Stability of the Protic Ionic Liquid Diethylmethylammonium Trifluoromethanesulfonate on Ag(111) and Au(111). S. Massicot, T. Sasaki, M. Lexow, S. Shin, F. Maier, S. Kuwabata, H.-P. Steinrück, Langmuir 2021, 37 (39), 11552-11560, https://doi.org/10.1021/acs.langmuir.1c01823, (Project: C02)
C02*: Cooperation publications (publications covering the entire CLINT environment)
C03: Molecular interactions and reaction mechanisms in Advanced SCILLs: From ideal model experiments to real materials and operando studies
In Project C03, we will elucidate the fundamental interaction mechanisms between functionalised ILs and catalytically active surfaces and their role in catalytic hydrogenation. To this aim, we will combine in situ studies at single crystals and atomically defined model catalysts in UHV with operando spectroscopy on real SCILLs under true working conditions. Our key tools will be vibrational spectroscopy (IRAS, PM-IRAS, DRIFTS) in combination with online analytics of products (MB experiments, TPD, TPR, online GC, online QMS). Specifically, we will identify interaction mechanisms at the surface, the orientation of IL ions, conformational changes, specific interactions with co-adsorbates, reaction intermediates and selectivity patterns.
Project Leaders
Publications:
C03: Core publications of this project (directly address the working programme of this project)
- Adsorption Motifs and Molecular Orientation at the Ionic Liquid/Noble Metal Interface: [C2C1Im][NTf2] on Pt(111). C. Hohner, L. Fromm, C. Schuschke, N. Taccardi, T. Xu, P. Wasserscheid, A. Görling, J. Libuda, Langmuir 2021, 37 (43), 12596-12607, http://dx.doi.org/10.1021/acs.langmuir.1c01900, (Project: C03, C05*, M01)
- Interaction between Ionic Liquids and a Pt(111) Surface Probed by Coadsorbed CO as a Test Molecule. R. Eschenbacher, C. Schuschke, H. Bühlmeyer, N. Taccardi, P. Wasserscheid, T. Bauer, T. Xu, J. Libuda, The Journal of Physical Chemistry Letters 2021, 12 (41), 10079-10085, http://dx.doi.org/10.1021/acs.jpclett.1c02983, (Project: C03, C05*)
- CO Permeability and Wetting Behavior of Ionic Liquids on Pt(111): An IRAS and PM-IRAS Study from Ultrahigh Vacuum to Ambient Pressure. D. Blaumeiser, C. Schuschke, L. Fromm, N. Taccardi, S. Schötz, R. Eschenbacher, H. Bühlmeyer, T. Xu, T. Bauer, P. Wasserscheid, A. Görling, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (28), 15301-15315, http://dx.doi.org/10.1021/acs.jpcc.1c04043, (Project: C03, M01)
- A Molecular View of the Ionic Liquid Catalyst Interface of SCILLs: Coverage-Dependent Adsorption Motifs of [C4C1Pyr][NTf2] on Pd Single Crystals and Nanoparticles. C. Schuschke, L. Fromm, J. Träg, C. Stumm, C. Hohner, R. Eschenbacher, S. Grau, D. Zahn, A. Görling, T. Bauer, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (24), 13264-13272, http://dx.doi.org/10.1021/acs.jpcc.1c02131, (Project: C03, M01, M03)
C03*: Cooperation publications (publications covering the entire CLINT environment)
- Pd/Co3O4(111) Interface Formation. M. Kastenmeier, L. Fusek, F. Mohamed, C. Schuschke, M. Ronovský, T. Skála, M. Farnesi Camellone, N. Tsud, V. Johánek, S. Fabris, J. Libuda, S. Piccinin, Y. Lykhach, J. Mysliveček, O. Brummel, The Journal of Physical Chemistry C 2023, 127 (12), 6034-6044, https://doi.org/10.1021/acs.jpcc.3c00261, (Project: C03*)
- Supraparticles for naked‑eye H2 indication and monitoring: improving performance by variation of the catalyst nanoparticles. K. Zhang, S. Schötz, J. Reichstein, P. Groppe, N. Stockinger, S. Wintzheimer, K. Mandel, J. Libuda, T. Retzer, The Journal of Chemical Physics 2023, 158 (13), 134722, http://dx.doi.org/10.1063/5.0135130, (Project: C03*)
- A Versatile Approach to Electrochemical In-situ Ambient-Pressure X-ray Photoelectron Spectroscopy: Application to a Complex Model Catalyst. O. Brummel, Y. Lykhach, M. Ralaiarisoa, M. Berasategui, M. Kastenmeier, L. Fusek, A. Simanenko, W. Gu, P. C. J. Clark, R. Yivlialin, M. J. Sear, J. Mysliveček, M. Favaro, D. E. Starr, J. Libuda, The Journal of Physical Chemistry Letters 2022, 13 (47), 11015-11022, http://dx.doi.org/10.1021/acs.jpclett.2c03004, (Project: C03*, C05)
- Improving the Performance of Supported Ionic Liquid Phase Catalysts for the Ultra-Low-Temperature Water Gas Shift Reaction Using Organic Salt Additives. P. Wolf, C. R. Wick, J. Mehler, D. Blaumeiser, S. Schötz, T. Bauer, J. Libuda, D. Smith, A.-S. Smith, M. Haumann, ACS Catal 2022, 12 (9), 5661-5672, https://doi.org/10.1021/acscatal.1c05979, (Project: B06*, C03*, C05*, M02)
- Adsorption and Reaction of NH3 on Rutile TiO2(110): An STM Study. H. Bühlmeyer, K. C. Adamsen, T. Xu, L. Lammich, J. Libuda, J. V. Lauritsen, S. Wendt, The Journal of Physical Chemistry C 2022, 126 (15), 6590-6600, http://dx.doi.org/10.1021/acs.jpcc.2c01414, (Project: C03*, C05*)
- Supraparticles for Bare‐Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. J. Reichstein, S. Schötz, M. Macht, S. Maisel, N. Stockinger, C. C. Collados, K. Schubert, D. Blaumeiser, S. Wintzheimer, A. Görling, M. Thommes, D. Zahn, J. Libuda, T. Bauer, K. Mandel, Advanced Functional Materials 2022, 32 (22), 2112379, http://dx.doi.org/10.1002/adfm.202112379, (Project: A05, C03*, C05*, M01*, M03*)
- Adsorption of D2O and CO on Co3O4(111): Water Stabilizes Co-adsorbed CO. G. Fickenscher, C. Hohner, T. Xu, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (48), 26785-26792, http://dx.doi.org/10.1021/acs.jpcc.1c07393, (Project: C03*)
C04: Understanding surface modification and stability of Advanced SCILL
Project C04 will target the stability of advanced SCILLs in hydrogenation reactions both with and without potential control. Depending on the catalyst material, reaction, and operation conditions, functionalised ILs may have a beneficial or a detrimental effect on the stability of the active NPs. Therefore, we will study the dynamic evolution of the catalytic interface over extended operation periods, in dependence of parameters such as the EC potential, composition, structure, morphology, and the chemical nature of the interface, and investigate the effect on the reactions in Projects C01 and C05. The project will benefit from the complementary expertise of the Mayrhofer and Virtanen groups, bringing together a broad range of methods to study dissolution, degradation and corrosion mechanisms.
Project Leaders
Publications:
C04: Core publications of this project (directly address the working programme of this project)
- Respirometric in Situ Methods for Real-Time Monitoring of Corrosion Rates: Part III. Deconvolution of Electrochemical Polarization Curves. M. G. Strebl, M. P. Bruns, S. Virtanen, Journal of The Electrochemical Society 2023, 170 (6), 061503, http://dx.doi.org/10.1149/1945-7111/acd665, (Project: C04)
- Coupling Respirometric HER and ORR Monitoring with Electrochemical Measurements. M. Strebl, M. Bruns, S. Virtanen, Electrochimica Acta 2022, 412, 140152, http://dx.doi.org/10.1016/j.electacta.2022.140152, (Project: C04)
C04*: Cooperation publications (publications covering the entire CLINT environment)
- Reduction of Oxide Layers on Au(111): The Interplay between Reduction Rate, Dissolution, and Restructuring. C. Stumm, S. Grau, F. D. Speck, F. Hilpert, V. Briega-Martos, K. Mayrhofer, S. Cherevko, O. Brummel, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (41), 22698-22704, https://doi.org/10.1021/acs.jpcc.1c03969, (Project: C04*)
C05: Advanced SCILLs in electrosynthesis: Understanding and tailoring selective hydrogenation and dehydrogenation at ionic liquid interfaces
In Project C05, we will explore the potential of Advanced SCILLs in electrocatalytic hydrogenation. Using a broad range of EC in situ spectroscopies, microscopies, and advanced EC characterisation methods, we will scrutinise the selective hydrogenation of unsaturated ketones and nitriles on a broad range of test electrodes (single crystals, atomically defined model electrodes, complex alloys and supported nanoalloys). At the electrified interface, we will explore (i) how ILs interact with specific sites at the electrode, (ii) how ILs interact with reactants during the electrocatalytic reaction, (iii) how these interactions affect the mechanism and kinetics, and (iv) how ILs can be tailored to enhance the selectivity of electrohydrogenation.
Project Leaders
- Prof. Dr. Olga Kasian (Website: http://www.i-meet.ww.fau.de)
Publications:
C05: Core publications of this project (directly address the working programme of this project)
- A Versatile Approach to Electrochemical In-situ Ambient-Pressure X-ray Photoelectron Spectroscopy: Application to a Complex Model Catalyst. O. Brummel, Y. Lykhach, M. Ralaiarisoa, M. Berasategui, M. Kastenmeier, L. Fusek, A. Simanenko, W. Gu, P. C. J. Clark, R. Yivlialin, M. J. Sear, J. Mysliveček, M. Favaro, D. E. Starr, J. Libuda, The Journal of Physical Chemistry Letters 2022, 13 (47), 11015-11022, http://dx.doi.org/10.1021/acs.jpclett.2c03004, (Project: C03*, C05)
- A combined rotating disk electrode–surface x-ray diffraction setup for surface structure characterization in electrocatalysis. L. Jacobse, R. Schuster, J. Pfrommer, X. Deng, S. Dolling, T. Weber, O. Gutowski, A.-C. Dippel, O. Brummel, Y. Lykhach, H. Over, J. Libuda, V. Vonk, A. Stierle, Review of Scientific Instruments 2022, 93 (6), 065111, http://dx.doi.org/10.1063/5.0087864, (Project: C05)
- Modifying the Electrocatalytic Selectivity of Oxidation Reactions with Ionic Liquids. T. Yang, J. Yang, X. Deng, E. Franz, L. Fromm, N. Taccardi, Z. Liu, A. Görling, P. Wasserscheid, O. Brummel, J. Libuda, Angew Chem Int Ed Engl 2022, 61 (29), e202202957, https://doi.org/10.1002/anie.202202957, (Project: C01, C05, M01)
C05*: Cooperation publications (publications covering the entire CLINT environment)
- Mechanistic Insight into Solution-Based Atomic Layer Deposition of CuSCN Provided by In Situ and Ex Situ Methods. F. Hilpert, P.-C. Liao, E. Franz, V. M. Koch, L. Fromm, E. Topraksal, A. Görling, A.-S. a. Smith, M. K. S. Barr, J. Bachmann, O. Brummel, J. Libuda, ACS Applied Materials & Interfaces 2023, 15 (15), 19536-19544, https://doi.org/10.1021/acsami.2c16943, (Project: C05*, M01*, M02*)
- Tunable Energy Release in a Reversible Molecular Solar Thermal System. E. Franz, C. Stumm, F. Waidhas, M. Bertram, M. Jevric, J. Orrego-Hernández, H. Hölzel, K. Moth-Poulsen, O. Brummel, J. Libuda, ACS Catal 2022, 12 (21), 13418-13425, http://dx.doi.org/10.1021/acscatal.2c03043, (Project: C05*)
- Electrochemically Triggered Energy Release from an Azothiophene-Based Molecular Solar Thermal System. E. Franz, A. Kunz, N. Oberhof, A. H. Heindl, M. Bertram, L. Fusek, N. Taccardi, P. Wasserscheid, A. Dreuw, H. A. Wegner, O. Brummel, J. Libuda, ChemSusChem 2022, 15 (18), e202200958, https://doi.org/10.1002/cssc.202200958, (Project: C05*)
- Particle Size and Shape Effects in Electrochemical Environments: Pd Particles Supported on Ordered Co3O4(111) and Highly Oriented Pyrolytic Graphite. M. Kastenmeier, L. Fusek, X. Deng, T. Skála, S. Mehl, N. Tsud, S. Grau, C. Stumm, V. Uvarov, V. Johánek, J. Libuda, Y. Lykhach, J. Mysliveček, O. Brummel, The Journal of Physical Chemistry C 2022, 126 (30), 12870-12881, http://dx.doi.org/10.1021/acs.jpcc.2c03109, (Project: C05*)
- Improving the Performance of Supported Ionic Liquid Phase Catalysts for the Ultra-Low-Temperature Water Gas Shift Reaction Using Organic Salt Additives. P. Wolf, C. R. Wick, J. Mehler, D. Blaumeiser, S. Schötz, T. Bauer, J. Libuda, D. Smith, A.-S. Smith, M. Haumann, ACS Catal 2022, 12 (9), 5661-5672, https://doi.org/10.1021/acscatal.1c05979, (Project: B06*, C03*, C05*, M02)
- Adsorption and Reaction of NH3 on Rutile TiO2(110): An STM Study. H. Bühlmeyer, K. C. Adamsen, T. Xu, L. Lammich, J. Libuda, J. V. Lauritsen, S. Wendt, The Journal of Physical Chemistry C 2022, 126 (15), 6590-6600, http://dx.doi.org/10.1021/acs.jpcc.2c01414, (Project: C03*, C05*)
- Operando Identification of the Reversible Skin Layer on Co3O4 as a Three-Dimensional Reaction Zone for Oxygen Evolution. T. Wiegmann, I. Pacheco, F. Reikowski, J. Stettner, C. Qiu, M. Bouvier, M. Bertram, F. Faisal, O. Brummel, J. Libuda, J. Drnec, P. Allongue, F. Maroun, O. M. Magnussen, ACS Catal 2022, 12 (6), 3256-3268, https://doi.org/10.1021/acscatal.1c05169, (Project: C05*)
- Supraparticles for Bare‐Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. J. Reichstein, S. Schötz, M. Macht, S. Maisel, N. Stockinger, C. C. Collados, K. Schubert, D. Blaumeiser, S. Wintzheimer, A. Görling, M. Thommes, D. Zahn, J. Libuda, T. Bauer, K. Mandel, Advanced Functional Materials 2022, 32 (22), 2112379, http://dx.doi.org/10.1002/adfm.202112379, (Project: A05, C03*, C05*, M01*, M03*)
- The role of defects in the photoconversion of 2-propanol on rutile titania: Operando spectroscopy combined with elementary studies. J. Kräuter, E. Franz, F. Waidhas, O. Brummel, J. Libuda, K. Al-Shamery, Journal of Catalysis 2022, 406, 134-144, http://dx.doi.org/10.1016/j.jcat.2021.12.025, (Project: C05*)
- Adsorption Motifs and Molecular Orientation at the Ionic Liquid/Noble Metal Interface: [C2C1Im][NTf2] on Pt(111). C. Hohner, L. Fromm, C. Schuschke, N. Taccardi, T. Xu, P. Wasserscheid, A. Görling, J. Libuda, Langmuir 2021, 37 (43), 12596-12607, http://dx.doi.org/10.1021/acs.langmuir.1c01900, (Project: C03, C05*, M01)
- Interaction between Ionic Liquids and a Pt(111) Surface Probed by Coadsorbed CO as a Test Molecule. R. Eschenbacher, C. Schuschke, H. Bühlmeyer, N. Taccardi, P. Wasserscheid, T. Bauer, T. Xu, J. Libuda, The Journal of Physical Chemistry Letters 2021, 12 (41), 10079-10085, http://dx.doi.org/10.1021/acs.jpclett.1c02983, (Project: C03, C05*)
Area M: Modelling and simulation
M01: Atomistic investigations of catalysis at liquid interfaces by density-functional calculations
The project aims at a microscopic quantum mechanical description of catalytic materials and processes in the three Areas A, B, and C (SCALMS, Interface-enhanced SILP, and Advanced SCILL). We will interpret and explain experimental data and develop and suggest strategies to optimise catalytic materials and processes. Based on conventional and newly developed density-functional methods (i) ab initio molecular dynamics simulations will be performed and (ii) slab and cluster models as well as (iii) molecular systems will be studied. Detailed atomistic information on catalytic sites, reaction steps, and diffusion and segregation processes as well as input for other theory projects in Area M will be provided.
Project Leaders
Publications:
M01: Core publications of this project (directly address the working programme of this project)
- Structure and Reactivity of the Ionic Liquid [C1C1Im][Tf2N] on Cu(111). R. Adhikari, S. Massicot, L. Fromm, T. Talwar, A. Gezmis, M. Meusel, A. Bayer, S. Jaekel, F. Maier, A. Görling, H.-P. Steinrück, Topics in Catalysis 2023, 1-18, https://doi.org/10.1007/s11244-023-01801-y, (Project: C02, M01)
- Isolated Rh atoms in dehydrogenation catalysis. H. Wittkämper, R. Hock, M. Weißer, J. Dallmann, C. Vogel, N. Raman, N. Tacardi, M. Haumann, P. Wasserscheid, T.-E. Hsieh, S. Maisel, M. Moritz, C. Wichmann, J. Frisch, M. Gorgoi, R. G. Wilks, M. Bär, M. Wu, E. Spiecker, A. Görling, T. Unruh, H.-P. Steinrück, C. Papp, Scientific Reports 2023, 13 (1), 4458, https://doi.org/10.1038/s41598-023-31157-y, (Project: A01, A02*, A03, A06, B06*, M01)
- Wilkinson-type catalysts in ionic liquids for hydrogenation of small alkenes: understanding and improving catalyst stability. E. Kratzer, S. Schoetz, S. Maisel, D. Blaumeiser, S. Khan Antara, L. Ewald, D. Dotzel, M. Haumann, A. Görling, W. Korth, A. Jess, T. Retzer, Catal Sci Technol 2023, 13 (7), 2053-2069, http://dx.doi.org/10.1039/d2cy02058k, (Project: B06, M01)
- Geometries and vibrational frequencies with Kohn–Sham methods using σ-functionals for the correlation energy. C. Neiss, S. Fauser, A. Görling, The Journal of Chemical Physics 2023, 158 (4), 044107, https://doi.org/10.1063/5.0129524, (Project: M01)
- Scaled sigma-functionals for the Kohne-Sham correlation energy with scaling functions from the homogeneous electron gas. J. Erhard, S. Fauser, E. Trushin, A. Görling, The Journal of Chemical Physics 2022, 157 (11), 114105, http://dx.doi.org/10.1063/5.0101641, (Project: M01)
- Numerically stable inversion approach to construct Kohn–Sham potentials for given electron densities within a Gaussian basis set framework. J. Erhard, E. Trushin, A. Görling, The Journal of Chemical Physics 2022, 156 (20), 204124, http://dx.doi.org/10.1063/5.0087356, (Project: M01)
- Modifying the Electrocatalytic Selectivity of Oxidation Reactions with Ionic Liquids. T. Yang, J. Yang, X. Deng, E. Franz, L. Fromm, N. Taccardi, Z. Liu, A. Görling, P. Wasserscheid, O. Brummel, J. Libuda, Angew Chem Int Ed Engl 2022, 61 (29), e202202957, https://doi.org/10.1002/anie.202202957, (Project: C01, C05, M01)
- Temperature-dependent XPS studies on Ga-In alloys through the melting-point. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Surface Science 2022, 717, 122008, http://dx.doi.org/10.1016/j.susc.2021.122008, (Project: A01, A06, M01)
- Adsorption Motifs and Molecular Orientation at the Ionic Liquid/Noble Metal Interface: [C2C1Im][NTf2] on Pt(111). C. Hohner, L. Fromm, C. Schuschke, N. Taccardi, T. Xu, P. Wasserscheid, A. Görling, J. Libuda, Langmuir 2021, 37 (43), 12596-12607, http://dx.doi.org/10.1021/acs.langmuir.1c01900, (Project: C03, C05*, M01)
- Surface oxidation-induced restructuring of liquid Pd–Ga SCALMS model catalysts. H. Wittkämper, S. Maisel, M. Moritz, M. Grabau, A. Görling, H.-P. Steinrück, C. Papp, Physical Chemistry Chemical Physics 2021, 23 (30), 16324-16333, http://dx.doi.org/10.1039/d1cp02458b, (Project: A01, A06, M01)
- CO Permeability and Wetting Behavior of Ionic Liquids on Pt(111): An IRAS and PM-IRAS Study from Ultrahigh Vacuum to Ambient Pressure. D. Blaumeiser, C. Schuschke, L. Fromm, N. Taccardi, S. Schötz, R. Eschenbacher, H. Bühlmeyer, T. Xu, T. Bauer, P. Wasserscheid, A. Görling, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (28), 15301-15315, http://dx.doi.org/10.1021/acs.jpcc.1c04043, (Project: C03, M01)
- A Molecular View of the Ionic Liquid Catalyst Interface of SCILLs: Coverage-Dependent Adsorption Motifs of [C4C1Pyr][NTf2] on Pd Single Crystals and Nanoparticles. C. Schuschke, L. Fromm, J. Träg, C. Stumm, C. Hohner, R. Eschenbacher, S. Grau, D. Zahn, A. Görling, T. Bauer, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (24), 13264-13272, http://dx.doi.org/10.1021/acs.jpcc.1c02131, (Project: C03, M01, M03)
M01*: Cooperation publications (publications covering the entire CLINT environment)
- Mechanistic Insight into Solution-Based Atomic Layer Deposition of CuSCN Provided by In Situ and Ex Situ Methods. F. Hilpert, P.-C. Liao, E. Franz, V. M. Koch, L. Fromm, E. Topraksal, A. Görling, A.-S. a. Smith, M. K. S. Barr, J. Bachmann, O. Brummel, J. Libuda, ACS Applied Materials & Interfaces 2023, 15 (15), 19536-19544, https://doi.org/10.1021/acsami.2c16943, (Project: C05*, M01*, M02*)
- Elucidating activating and deactivating effects of carboxylic acids on polyoxometalate-catalysed three-phase liquid–liquid-gas reactions. M. J. Poller, S. Bönisch, B. Bertleff, J. C. Raabe, A. Görling, J. Albert, Chemical Engineering Science 2022, 264, 118143, http://dx.doi.org/10.1016/j.ces.2022.118143, (Project: M01*)
- Electrocatalytic Energy Release of Norbornadiene-Based Molecular Solar Thermal Systems: Tuning the Electrochemical Stability by Molecular Design. E. Franz, D. Krappmann, L. Fromm, T. Luchs, A. Görling, A. Hirsch, O. Brummel, J. Libuda, ChemSusChem 2022, 15 (24), e202201483-e202201483, https://doi.org/10.1002/cssc.202201483, (Project: M01*)
- Triggering the energy release in molecular solar thermal systems: Norbornadiene-functionalized trioxatriangulen on Au(111). R. Eschenbacher, T. Xu, E. Franz, R. Löw, T. Moje, L. Fromm, A. Görling, O. Brummel, R. Herges, J. Libuda, Nano Energy 2022, 95, 107007, https://www.sciencedirect.com/science/article/pii/S2211285522000921, (Project: M01*)
- Supraparticles for Bare‐Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. J. Reichstein, S. Schötz, M. Macht, S. Maisel, N. Stockinger, C. C. Collados, K. Schubert, D. Blaumeiser, S. Wintzheimer, A. Görling, M. Thommes, D. Zahn, J. Libuda, T. Bauer, K. Mandel, Advanced Functional Materials 2022, 32 (22), 2112379, http://dx.doi.org/10.1002/adfm.202112379, (Project: A05, C03*, C05*, M01*, M03*)
M02: Multiscale modelling of SILP and SCILL catalysis
Project M02 focusses on multi-scale simulations in the field of SILP and SCILL catalysis for tuning of the catalytic complex, the IL, and the support material in order to maximise efficiency of reactions studied in C01 and B06. This requires the development of hybrid quantum mechanics/ molecular mechanics approaches to embed the local quantum description of the reactive centre into the surrounding IL film. Molecular dynamics simulations will be used to enhance the spatial coordination of the reactants with the interfaces, by investigation of the structural and transport properties of IL and reactants. Molecular simulations of IL interface dynamics shall be used to parametrise the lattice-Boltzmann models in M04.
Project Leaders
Publications:
M02: Core publications of this project (directly address the working programme of this project)
- Bis-polyethylene glycol-functionalized imidazolium ionic liquids: A multi-method approach towards bulk and surface properties. V. Seidl, M. Bosch, U. Paap, M. Livraghi, Z. Zhai, C. R. Wick, T.-M. Koller, P. Wasserscheid, F. Maier, A.-S. Smith, J. Bachmann, H.-P. Steinrück, K. Meyer, Journal of Ionic Liquids 2022, 2 (2), 100041, http://dx.doi.org/10.1016/j.jil.2022.100041, (Project: A04*, B01, B04, M02)
- Improving the Performance of Supported Ionic Liquid Phase Catalysts for the Ultra-Low-Temperature Water Gas Shift Reaction Using Organic Salt Additives. P. Wolf, C. R. Wick, J. Mehler, D. Blaumeiser, S. Schötz, T. Bauer, J. Libuda, D. Smith, A.-S. Smith, M. Haumann, ACS Catal 2022, 12 (9), 5661-5672, https://doi.org/10.1021/acscatal.1c05979, (Project: B06*, C03*, C05*, M02)
- From Water Solutions to Ionic Liquids with Solid State Nanopores as a Perspective to Study Transport and Translocation Phenomena. S. Marion, N. Vučemilović‐Alagić, M. Špadina, A. Radenović, A.-S. Smith, Small 2021, 17 (25), 2100777, http://dx.doi.org/10.1002/smll.202100777, (Project: M02)
M02*: Cooperation publications (publications covering the entire CLINT environment)
- Mechanistic Insight into Solution-Based Atomic Layer Deposition of CuSCN Provided by In Situ and Ex Situ Methods. F. Hilpert, P.-C. Liao, E. Franz, V. M. Koch, L. Fromm, E. Topraksal, A. Görling, A.-S. a. Smith, M. K. S. Barr, J. Bachmann, O. Brummel, J. Libuda, ACS Applied Materials & Interfaces 2023, 15 (15), 19536-19544, https://doi.org/10.1021/acsami.2c16943, (Project: C05*, M01*, M02*)
M03: Molecular dynamics simulations of SCALMS, SCILL and SILP: Specific interactions, cooperative effects, self-organisation, and catalytic mechanisms
Project M03 will perform molecular dynamics simulations for the in-depth understanding of effects that occur at the nanometre scale such as the self-organisation of IL layers and films (Kawska-Zahn approach). To account for charge polarisation in metal droplets and nanoparticles, the MM models will be extended by QeQ approaches. This effectively expands QM characterisation to MD simulations reaching the million atoms scale. Using multi-state MM models triggered by QM/MM calculations, the relaxation dynamics of deactivation and self-healing reactions of the catalyst will be elucidated.
Project Leaders
Publications:
M03: Core publications of this project (directly address the working programme of this project)
- Thermal Stability and CO Permeability of [C4C1Pyr][NTf2]/Pd(111) Model SCILLs: from UHV to Ambient Pressure. R. Eschenbacher, S. Trzeciak, C. Schuschke, S. Schötz, C. Hohner, D. Blaumeiser, D. Zahn, T. Retzer, J. Libuda, Topics in Catalysis 2023, https://doi.org/10.1007/s11244-023-01798-4, (Project: M03)
- A Molecular View of the Ionic Liquid Catalyst Interface of SCILLs: Coverage-Dependent Adsorption Motifs of [C4C1Pyr][NTf2] on Pd Single Crystals and Nanoparticles. C. Schuschke, L. Fromm, J. Träg, C. Stumm, C. Hohner, R. Eschenbacher, S. Grau, D. Zahn, A. Görling, T. Bauer, J. Libuda, The Journal of Physical Chemistry C 2021, 125 (24), 13264-13272, http://dx.doi.org/10.1021/acs.jpcc.1c02131, (Project: C03, M01, M03)
M03*: Cooperation publications (publications covering the entire CLINT environment)
- Supraparticles for Bare‐Eye H2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. J. Reichstein, S. Schötz, M. Macht, S. Maisel, N. Stockinger, C. C. Collados, K. Schubert, D. Blaumeiser, S. Wintzheimer, A. Görling, M. Thommes, D. Zahn, J. Libuda, T. Bauer, K. Mandel, Advanced Functional Materials 2022, 32 (22), 2112379, http://dx.doi.org/10.1002/adfm.202112379, (Project: A05, C03*, C05*, M01*, M03*)
M04: Mesoscale simulation of wetting dynamics and interface reactivity
Project M04 will address mesoscale phenomena relevant to all experimental areas by means of lattice-Boltzmann simulations. The dynamics of wetting and dewetting of substrates by IL films and metal droplets will be elucidated driven by heat formation and mass transport during catalyst operation. M04 will assess contact angles and their variation depending on the geometry of porous supports, the dynamics of spreading and imbibition of ILs and liquid metals in such supports, the accessibility of surface sites, the heat flux, and the resulting turnover rates. Understanding the combination of these effects, we will rationalise experimental findings and propose strategies for the improvement of materials and processes.
Project Leaders
- Prof. Dr. Jens Harting (Website: http://www.hi-ern.de)
Publications:
M04: Core publications of this project (directly address the working programme of this project)
- Closed Formula for Transport across Constrictions. P. Malgaretti, J. Harting, Entropy 2023, 25 (3), 470, http://dx.doi.org/10.3390/e25030470, (Project: M04)
- Nucleation as a rate-determining step in catalytic gas generation reactions from liquid phase systems. T. Solymosi, M. Geißelbrecht, S. Mayer, M. Auer, P. Leicht, M. Terlinden, P. Malgaretti, A. Bösmann, P. Preuster, J. Harting, M. Thommes, N. Vogel, P. Wasserscheid, Sci Adv 2022, 8 (46), eade3262, https://doi.org/10.1126/sciadv.ade3262, (Project: A05, A06*, B03, M04)
- Pumping and Mixing in Active Pores. G. C. Antunes, P. Malgaretti, J. Harting, S. Dietrich, Physical Review Letters 2022, 129 (18), 188003 http://dx.doi.org/10.1103/physrevlett.129.188003, (Project: M04)
- Liquid film rupture beyond the thin-film equation: A multi-component lattice Boltzmann study. F. Pelusi, M. Sega, J. Harting, Physics of Fluids 2022, 34 (6), 062109, http://dx.doi.org/10.1063/5.0093043, (Project: M04)
M04*: Cooperation publications (publications covering the entire CLINT environment)
Central Projects
Z01: Management and organisation
Project Z01 comprises the scientific coordination of CLINT. The project targets include the administrative management, reporting, proposal preparation, measures related to internationalisation, public relations and outreach, science communication and dissemination. Furthermore, the project will provide professional quality assurance, will help to protect our inventions by IP rights, will act as central coordination point between all institutions, and will organise seminars by invited speakers, area meetings, workshops, retreats and conferences. We will place special emphasis on equal opportunity at all levels of qualification in accordance with our gender equality targets.
Project Leaders
MGK: Integrated Research Training Group CLINTiRTG ‘Catalysis Science and Technology’
The primary goal of the CLINTiRTG is to ensure a profound academic education and to provide qualifications that go beyond the usual training of young researchers. While primarily addressing doctoral students, CLINTiRTG will also support postdoctoral researchers and undergraduate students. For its participants, CLINTiRTG will provide a comprehensive training and networking programme that foremost expands their multidisciplinary academic competences in catalysis and related fields. A soft skills program will enable improving their capacities to lead, organise and communicate while promoting a progressive and diverse working environment. CLINTiRTG will boost the knowledge and independence of young researchers to create a next generation of experts working on the executive level in industry and academia.